104) Joseph, E.; Brar, D. S.; Stuhlsatz, G. "Transition Metal-Free Decarboxylative Olefination of Carboxylic Acid Salts" Chem. Sci.2024

Graphical abstract: Transition metal-free decarboxylative olefination of carboxylic acid salts

103) Joseph, E.; Smith, I.; Tunge, J. A. "Cobalt-catalyzed decarboxylative difluoroalkylation of nitrophenylacetic acid salts." Chem. Sci., 2023,13902-13907. 10.1039/D3SC05583C3

Graphical abstract: Cobalt-catalyzed decarboxylative difluoroalkylation of nitrophenylacetic acid salts

102) Davies, A. M.; Londhe, S. S.; Smith, E. R.; Tunge, J. A. "Single-Step Synthesis of γ-Ketoacids through a Photoredox-Catalyzed Dual Decarboxylative Coupling of α-Oxo Acids and Maleic Anhydrides." Org. Lett. 2023, 25, 8634-8639. 10.1021/acs.orglett.3c03258.

101) Joseph, E., Hernandez, R. D.; Tunge, J. A. "Cobalt‐catalyzed Decarboxylative Allylations: Development and Mechanistic Studies." Chem. Eur. J. 2023, 29, e2023021, 10.1002/CHEM.202302174

Description unavailable

100) Davies, A. M.; Hernandez, R. D.; Tunge, J. A. “Direct Aroylation of Olefins through a Cobalt/Photoredox-Catalyzed Decarboxylative and Dehydrogenative Coupling with α-Oxo AcidsChem. Eur. J. 2022. e202202781; Front cover

Description unavailable

99) Jiang, X.; Xiong, W.; Deng, S.; Lu, F.-D.; Jia, Y.; Yang, Q.; Xue, L.-Y.; Qi, X.; Tunge, J. A.; Lu, L.-Q.; Xiao, W.-J. “Construction of axial chirality via asymmetric radical trapping by cobalt under visible lightNat. Catal. 2022, 5, 788-797.

98) Jiang, X.; Jiang, H.; Yang, Q.; Cheng, Y.; Lu, L.-Q.; Tunge, J. A.; Xiao, W.-J. “Photoassisted Cobalt-Catalyzed Asymmetric Reductive Grignard-Type Addition of Aryl IodidesJ. Am. Chem. Soc.2022, 144, 8347-8354.

97) Cartwright, K. C.; Joseph, E.; Comadoll, C. G. “Photoredox/Cobalt Dual Catalyzed Decarboxylative Elimination of Carboxylic Acids: Development and Mechanistic InsightChem. Eur. J. 2020, 12454-12471.

96) Cartwright, K. C.; Tunge, J. A. “Organophotoredox/palladium dual catalytic decarboxylative Csp3-Csp3 coupling of carboxylic acids and pi-electrophilesChem. Sci.2020, 11, 8167-8175.

95. Tunge, J. A. "The Evolution of Decarboxylative Allylation: Overcoming pKa LimitationsIsr. J.Chem. 2020.  In honor of Profs. Hartwig and Buchwald receipt of the Wolf Prize

94. Cartwright, K. C.; Davies, A. M.; Tunge, J. A. "Cobaloxime-catalyzed Hydrogen Evolution in Photoredox-facilitated Small Molecule FunctionalizationEur. J. Org. Chem. 2020, 1186. Front cover and part of a ChemPhotoChem virtual collection on photochemical synthesis.

93. Senaweera, S.; Cartwright, K. C.;Tunge, J. A. "Decarboxylative Acetoxylation of Aliphatic Carboxylic AcidsJ. Org. Chem. 201984, 12553-12561.

92. Allegre, K.; Tunge, J. A. "Aryl Vinyl Cyclopropane Cope RearrangementsTetrahedron 201975, 3319-3329.  Special issue in honor of Ryan Shenvi's Young Investigator Award 

91. Cartwright, K. C.; Lang, S. B.; Tunge, J. A. "Photoinduced Kochi Decarboxylative Elimination for the Synthesis of Enamides and Enecarbamates from N-Acyl Amino AcidsJ. Org. Chem. 201984, 2933-2940.

90. Cartwright, K. C.; Tunge, J. A. "Decarboxylative Elimination of N-Acyl Amino Acids via Photoredox/Cobalt Dual CatalysisACS Catal20188, 11801-11806.

89. Allegre, K. A.; Brennan, N.; Tunge, J. A. "Synthesis of Vinyl Cyclopropanes via Anion Relay CyclizationOrg. Lett201820, 4191-4194.

88. Maity,P. K.; Tunge, J. A. "Assisted Tandem Catalytic Conversion of Acrylates into Adipic EstersChemCatChem 201810, 3419-3423.

87. Torregrosa, R. R. P.; Mendis, S. N.; Davies A.; Tunge, J. A. "Palladium-Catalyzed Decarboxylative Benzylation of Acetylides and EnolatesSynthesis 201850, 3205-3216. Published as part of the Special Topic Modern Coupling Approaches and their Strategic Applications in Synthesis, Erick M. Carreira Ed.

86. Li, T-R.; Maliszewski, M. L.;Xiao, W-J.; Tunge, J. A. "Stereospecific Decarboxylative Benzylation of Enolates: Development and Mechanistic InsightsOrg. Lett201820, 1730-1734.

85. Smith, M. K.; Tunge, J. A. "Palladium-Catalyzed Synthesis of Conjugated Allenynes via Decarboxylative CouplingOrg. Lett201719, 5497-5500.

84. Ramakumar, K.; Maji, T.; Partridge, J. J.; Tunge, J. A. "Synthesis of Spiroxindoles via the tert-Amino EffectOrg. Lett. 201719, 4014-4017.

83. Locascio, T. M.; Tunge, J. A. "Palladium-catalyzed Regiodivergent Substitution of Propargylic CarbonatesChem. Eur. J201622, 18140-18146.

82. Maji, T.; Mendis, C. H.; Thompson, W. H.; Tunge, J. A. "Evidence for Isomerizing Hydroformylation of Butadiene. A Combined Experimental and Computational StudyJ. Mol. Catal. A 2016424, 145-152.

81. Maji, T.; Maliszewski, M. L.; Smith, M. K.; Tunge, J. A. "Catalytic Addition of Fluorinated Benzoic Acids to Butadiene" ChemCatChem 2016, 3343-3346.  Highlighted by ChemistryViews.

80. Lang, S. B.; Cartwright, K. C.; Welter, R. S.; Locascio, T. M.; Tunge, J. A. "Photocatalytic Aminodecarboxylation of Carboxylic AcidsEur. J. Org. Chem20162016, 3331-3334.

79. Mendis, S. N.; Tunge, J. A. "Decarboxylative dearomatization and mono-alpha-arylation of ketonesChem. Commun2016, 7695-7698.

78. Lang, S. B.; O'Nele, K. M.; Douglas, J. T.; Tunge, J. A. "Dual Catalytic Decarboxylative Allylation of alpha-Amino Acids and Their Divergent MechanismsChem. Eur. J201521, 18589-18593.

77. Mendis, S.; Tunge, J. A. "Palladium-catalyzed Stereospecific Decarboxylative Benzylation of Alkynes" Org. Lett. 201517, 5164-5167.

76. Maji, T.; Tunge, J. A. "Palladium-catalyzed Double-decarboxylative Addition to Pyrones:  Synthesis of Conjugated Dienoic Esters" Org. Lett. 201517, 4766-4769.

75. Wu, X.; Lan, L.; Wilson, D. M.; Marquez, R. T.; Tsao, W.-c.; Gao, R.; Roy, A.; Turner, B. A.; McDonald, R. Tunge, J. A.; Rogers, S. A.; Dixon, D. A.; Aube, J.; Xu, L. "Identification and validation of novel small molecule disruptors of HuR-mRNA InteractionACS Chem. Biol. 201510, 1476-1484.

74. Lang, S. B.; O'Nele, K. M.; Tunge, J. A. "Decarboxylative allylation of amino alkanoic acids and esters via dual catalysisJ. Am. Chem. Soc2014136, 13606-9.

73. Maji, T.; Ramakumar, K.; Tunge, J. A. "Retro-Claisen benzylation: direct use of benzyl alcohols in Pd-catalyzed couplings with nitrilesChem. Commun. 2014, 14045-8.

72. Ariyarathna, Y.; Tunge, J. A. "Multicomponent decarboxylative allylationsChem. Commun2014, 14049-14052.

71. Maji, T.; Tunge, J. A. "Catalytic alpha-monoallylation of aryl acetonitrilesOrg. Lett201416, 5072-5075.

70. Ariyarathna, Y.; Tunge, J. A. "Decarboxylative allylations of ester enolate equivalentsOrg. Biomol. Chem2014, 8386-8389.

69. Ramakumar, K.; Tunge, J. A. "Synthesis of N-aryl-1-aminoindoles via intermolecular redox aminationChem. Commun201450, 13056-13058.

68.  Lang, S. B.; Locascio, T. M.; Tunge, J. A. "Activation of alcohols with carbon dioxide: Intermolecular allylation of weakly acidic pronucleophilesOrg. Lett201416, 4308-4311.

67.  Xie, Z.; Fang, J.; Subramaniam, B.; Maiti, S. K.; Snavely, W.; Tunge, J. A. "Enhanced hydroformylation by carbon dioxide-expanded media with soluble Rh complexes in nanofiltration membrane reactorsAIChE J. 201359, 4287-4296.

66.  Grenning, A. J.; Van Allen, C. K.; Maji, T.; Lang, S. B.; Tunge, J. A. "Development of asymmetric deacylative allylationJ. Org. Chem. 201378, 7281-7287.

65.  Chattopadhyay, K.; Fenster, E.; Grenning, A. J.; Tunge, J. A. "Palladium-catalyzed substitution of (coumarinyl)methyl acetates with C-, N-, and S-nucleophilesBeilstein J. Org. Chem. 20128, 1200-1207.

64.  Chattopadhyay, K.; Recio, A., III; Tunge, J. A. "Palladium-catalyzed, pyrrolidine mediated arylmethylation of ketones and aldehydes with coumarinyl(methyl) acetatesOrg. Biomol. Chem201210, 6826-6829.

63.  Dunn, E.; Tunge, J. "Decarboxylative Allylation of Ketone Enolates with Rh, Ir, and MoLatvian J. Chem2012, 31.

62.  Schmitt, M.; Grenning, A. J.; Tunge, J. A. "Intercepted decarboxylative allylations of nitroalkanesTetrahedron Lett201253, 4494-4497.

61.  Recio, A. III; Heinzman, J. D.; Tunge, J. A. "Decarboxylative benzylation and arylation of nitrilesChem. Commun2012, 142-144.

60.  Jana, R.; Tunge, J. A. "A homogeneous, recyclable polymer support for Rh(I)-catalyzed C-C bond formationJ. Org. Chem201176, 8376-8385.

59.  Grenning, A. J.; Tunge, J. A. "Deacylative allylation: allylic alkylation via retro-Claisen activationJ. Am. Chem. Soc2011133, 14785-14794.

58.  Jana, R.; Tunge, J. A. “Migratory decarboxylative coupling of coumarins: synthetic and mechanistic aspects“  Angew. Chem. Int. Ed201150, 5157-5161.

57.  Grenning, A. J.; Tunge, J. A. “Deacylative allylation of nitroalkanes: Unsymmetric bisallylation by a three-component coupling” Angew. Chem. Int. Ed. 201150, 1688-1691.

56.  Weaver, J. D.; Recio III, A.; Grenning, A. J.; Tunge, J. A. “Transition Metal-catalyzed Decarboxylative Allylation and Benzylation Reactions” Chem. Rev. 2011111, 1846-1913.

55.   Fang, J.; Jana, R.; Tunge, J. A.; Subramaniam, B. “Continuous hoomogeneous hydroformylation with bulky rhodium catalyst complexes retained by nano-filtration membranes“  Appl. Catal. A 2011393, 294-301.

54.  Weaver, J. D.; Ka, B. J.; Morris, D. K.; Thompson, W.; Tunge, J. A. “Stereospecific Decarboxylative Allylation of Sulfones” J. Am. Chem. Soc2010132, 12179-12181.

53.  Torregrosa, R. R. P.; Ariyarathna, Y.; Chattopadhyay, K.; Tunge, J. A. “Decarboxylative Benzylations of Alkynes and Ketones” J. Am. Chem. Soc. 2010132, 9280-9282.

52.  Tunge, J. A. “Tetra-3-chlorotetrakis[(1,2,3,4,5-)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]tetra-ruthenium” electronic-Encyclopaedia of Reagents for Organic Synthesis (eEROS) 2010

51.  Chattopadhyay, K.; Jana, R.; Day, V. W.; Douglas, J. T.; Tunge, J. A. “Mechanistic Origin of the Stereodivergence in Decarboxylative Allylation” Org. Lett. 201012, 3042-3045.

50.   Grenning, A. J.; Tunge, J. A. “Rapid Decarboxylative Allylation of Nitroalkanes” Org. Lett201012, 740-742.

49.   Weaver, J. D.; Morris, D. K.; Tunge, J. A. “Synthesis of Chiral Nonracemic Tertiary α-Thio and α-Sulfonyl Acetic Esters via SN2 Reactions of Tertiary Mesylates” Synlett2010, 470-474.

48.   Pahadi, N. K.; Paley, M.; Jana, R.; Waetzig, S. R.; Tunge, J. A. “Formation of N-Alkylpyrroles via Intermolecular Redox Amination” J. Am. Chem. Soc2009131, 16626-16627.

47.   Recio III, A.;  Tunge, J. A. “Regiospecific Decarboxylative Allylation of Nitriles” Org. Lett200911, 5630-5633.

46.   Trivedi, R.; Tunge, J. A. “Regioselective Iron-catalyzed Decarboxylative Allylic Etherification” Org. Lett200911, 5650-5652.

45.   Pahadi, N. K.; Tunge, J. A. “Catalytic Intermolecular Hydroamination of Vinyl Ethers” Synlett 2009,  3135-3138.

44.   Jana, R.; Trivedi, R.; Tunge, J. A. “Mild Decarboxylative Coupling of Coumarins” Org. Lett200911, 3434-3436.

43.    Wang, R.; Cai, H.; Jin, H.; Xie, Z.; Subramaniam, B.; Tunge, J. A., “Hydroformylation in CO2-expanded media” ACS Symposium Series 2009, 1006 (Gas-Expanded Liquids and Near-Critical Media:  Green Chemistry and Engineering).

42.    Duan, S.; Jana, R.; Tunge, J. A. “Lewis acid-catalyzed diastereoselective hydroarylation of benzylidene malonic esters” J. Org. Chem200974, 4612-4614.

41.    Wang, C.; Pahadi, N.; Tunge, J. A. “Decarboxylative cyclizations and cycloadditions of palladium-polarized aza-ortho-xylylenes” Tetrahedron 200965, 5102-5109. (invited contribution to a Tetrahedron Young Investigator Symposium-in-print issue honoring Prof. Michael Krische)

40.    Jana, R.; Tunge, J. A. “A Homogeneous, Recyclable Rhodium(I) Catalyst for the Hydroarylation of Michael Acceptors“ Org. Lett. 200911, 971-974.

39.    Subramaniam, B.; Tunge, J.; Jin, H.; Ghosh, A. “Tuning Product Selectivity in Catalytic Hydroformylation Reactions with Carbon Dioxide Expanded Liquids.”  U. S. Patent 7,365,234, Issued April 29, 2008.

38.    Weaver, J. D.; Tunge, J. A. “Decarboxylative Allylation using Sulfones as Surrogates of Alkanes” Org. Lett200810, 4657-4660.

37.    Li, K.; Tunge, J. A. “Reduction of Pyrrolyl- and Indolylamides with BH3.THF: Cyclodeoxygenation versus Deoxygenation” J. Org. Chem. 200873, 8651-8653.

36.    Waetzig, Shelli R.; Tunge, Jon A. “Synthesis of allyl selenides by palladium-catalyzed decarboxylative coupling.” Chem. Comm. 2008, 3311-3313.

35.    Wang, C.; Tunge, J. A. “Asymmetric Cycloadditions of Palladium-Polarized Aza-o-xylylenes” J. Am. Chem. Soc. 2008130, 8118-8119.

34.    Li, K.; Tunge, J. A. “Chemical Libraries via Sequential C-H Functionalization of Phenols”  J. Comb. Chem. 200810, 170-174.

33.    Waetzig, S. R.; Tunge, J. A. “Palladium-Catalyzed Decarboxylative sp3-sp3 Coupling of Nitrobenzene Acetic Esters” J. Am. Chem. Soc. 2007129, 14860-14861.

32.    Waetzig, S. R.; Tunge, J. A. “Regio- and Diastereoselective Decarboxylative Coupling of Heteroaromatic Alkanes“ J. Am. Chem. Soc. 2007129, 4138-4139.

31.    Li, K.; Tunge, J. A. “Stereochemical Control in the Reduction of 2-Chromanols” Org. Lett20068, 4711-4714.

30.    Burger, E. C.; Barron, B. R.; Tunge, J. A. “Catalytic Asymmetric Synthesis of Cyclic alpha-Allylated alpha-Fluoroketones. Synlett 2006, 2824-2826.

29.    Yi L.; Dratter J.; Wang C., Tunge J.; Desaire H. “Identification of the biological effects of sulfation using tandem mass spectrometry” Anal. Bioanal. Chem2006. 386, 666-674.

28.    Wang, C.; Tunge, J. A. “Decarboxylative Ring Contractions and Olefin Insertions of Vinyl Oxazinanones” Org. Lett20068, 3211-3214.

27.    Burger, E., C.; Tunge, J. A. “Synthesis of Homoallylic Amines via the Palladium-catalyzed Decarboxylative Coupling of Amino Acids” J. Am. Chem. Soc. 2006 128, 10002-10003.

26.    Waetzig, S. R.; Rayabarapu, D. K.; Weaver, J. D.; Tunge, J. A. “A Versatile Hexadiene Synthesis via Decarboxylative sp3-sp3 Coupling/Cope Rearrangement” Angew. Chem. Int. Ed. 200645, 4977-4980.

25.    Mellegaard-Waetzig, S. R.; Wang, C.; Tunge, J. A. “Selenium-catalyzed Oxidative Halogenation” Tetrahedron 200662, 7191-7198.  (invited contribution to a Symposium-in-print issue)

24.    Jin, H.; Ghosh, A.; Tunge, J. A.; Subramaniam, B. “Intensification of catalytic olefin hydroformylation in CO2-expanded media” AIChE J. 200652, 2575-2581.

23.    Foresee, L. N.; Tunge, J. A. “Mechanistic Studies of Fujiwara Hydroarylation.  C-H Activation vs. Electrophilic Aromatic Substitution” Organometallics 200524, 6440-6444.

22.    Mellegaard-Waetzig, S. R.; Rayabarapu, D. K.; Tunge, J. A. “Allylic Amination via Decarboxylative C-N Bond Formation” Synlett 2005, 2759-2762.

21.    Rayabarapu, D. K.; Tunge, J. A. “Catalytic Decarboxylative sp-sp3 Coupling” J. Am. Chem. Soc2005127, 13510-13511.

20.    Li, K.; Zeng, Y.; Neuenswander, B.; Tunge, J. A. “Sequential Pd(II)-Pd(0) Catalysis for the Rapid Synthesis of Coumarins” J. Org. Chem. 200570, 6515-6518.

19.    Burger, E. C.; Tunge, J. A. “Ruthenium-catalyzed Stereospecific Decarboxylative Allylation of Non-stabilized Ketone Enolates” Chem. Commun2005, 2835-2837.

18.    Wang, C.; Tunge, J. A. “Ruthenium-catalyzed Decarboxylative Insertion of Electrophiles” Org. Lett. 20057, 2137-2139.

17.    Tunge, J. A.; Burger E. C. “Transition Metal Catalyzed Decarboxylative Additions of Enolates” Eur. J. Org. Chem. 2005, 1715-1726.

16.    Li, K.; Foresee, L. N.; Tunge, J. A., “Trifluoroacetic Acid-Mediated Hydroarylation: Synthesis of Dihydrocoumarins and Dihydroquinolones” J. Org. Chem200570, 2881-2883.

15.    Mellegaard, S. R.; Tunge, J. A. “Selenium-Catalyzed Halolactonization: Nucleophilic Activation of Electrophilic Halogenating Reagents” J. Org. Chem200469, 8979-8981.

14.    Burger, E. C.; Tunge, J. A. “Asymmetric Allylic Alkylation of Ketone Enolates: An Asymmetric Claisen Surrogate” Org. Lett20046, 4113-4115.

13.    Wang, C., Tunge, J. A. “Selenium-catalyzed alpha-Halogenation” Chem. Commun2004, 2694 - 2695.

12.    Burger, E. C.; Tunge, J. A. “Ruthenium-Catalyzed Decarboxylative Allylation of Nonstabilized Ketone Enolates” Org. Lett. 20046, 2603-2605.

11.    Tunge, J. A.; Mellegaard, S. R. “Selective Selenocatalytic Allylic Chlorination” Org. Lett. 20046, 1205-1207.

10.    Cummings, S. A.; Tunge, J. A.; Norton, J. R. “Direct measurement of the rate of interconversion of zirconaaziridine enantiomers”  J. Am. Chem. Soc. 2008130, 4669-4679.

9.    Cummings, S.; Tunge, J. A.; Norton, J. A. In New Aspects of Zirconium Containing Organic Compounds; Editor, Marek, I.; Topics in Organometallic Chemistry; Springer: 200510,  pp. 1-41.

8.    Casey, C. P.; Tunge, J. A.; Lee, T-Y.; Fagan, M. A.  “Structural Dependence of Thermodynamics of Alkene Binding to Yttrium Alkyl Complexes and of Kinetics of Alkyl Migration to Coordinated Alkenes” J. Am. Chem. Soc. 2003125, 2641-2651.

7.    Casey, C. P.; Tunge, J. A.; Fagan, M. A. “Why propene is not polymerized by (Cp*2YH)2:  Reactions of yttrium alkyl complexes with alkenes produce allyl and vinyl yttrium complexes” J. Organomet. Chem2002663, 91-97.

6.    Chen, J-X.; Tunge, J. A.; Norton, J. R. “Asymmetric Synthesis of Silylated a-Amino Acid Esters through Dynamic Kinetic Resolution” J. Org. Chem200267,  4366-69.

5.    Casey, C. P.; Tunge, J. A.; Lee, T-Y.; Carpenetti, D. W. “Kinetics and Mechanism of Formation of Yttrium Alkyl Complexes from (Cp2YH)2 and Alkenes” Organometallics 200221, 389-96.

4.    Casey, C. P.; Lee, T-Y.; Tunge, J. A.; Carpenetti, D. W.  “Direct Observation of a Nonchelated Metal-Alkyl-Alkene Complex and Measurement of the Rate of Alkyl Migration to a Coordinated Alkene” J. Am. Chem. Soc. 2001123, 10762-63.

3.    Tunge, J. A.; Czerwinski, C. J.; Gately, D. A.; Norton, J. R. “Mechanism of Insertion of Carbodiimides into the Zr-C Bonds of Zirconaaziridines. Formation of a-Amino Amidines” Organometallics 200120,  254-60.

2.    Harlan, C. J.; Tunge, J. A.; Bridgewater, B. M.; Norton, J. R. “Trapping of Acetylene by a Zirconocene Terminal Imido Complex” Organometallics 200019, 2365-72.

1.    Tunge, J. A.; Gately, D. A.; Norton, J. R. “Asymmetric Formation of a-Amino Acid Esters through Dynamic Kinetic Resolution: A Cyclic Carbonate as an Optically Active CO2 Synthon” J. Am. Chem. Soc. 1999121, 4520-21.